i just wanted to make a few comment that will hopefully help someone.
firstly, 100% silicone is not automatically ok. some will say 100% and mold inhibitor. i don't see how they can really justify this, but they do.
secondly, almost any play sand you get will do nothing significant to the water. they will generally increase ph and add silicates to the water, but this is so small it's nothing you would be able to read anyway. lime stone and aragonite, or similar types of sand, will increase ph somewhat, but this is generally in very long term uses, and with reduced water changes. i don't have any practical experience with amphibians yet, just a lot with fresh/saltwater fish/plants, i would think that the water exchanges you would have to do to reduce toxins would pretty much cover it.
third, a question, i like tannic peat moss and tannic acids, it has a mild sterilizing affect and many animals enjoy it. the amount of ph that it drops is usually not much or desirable, but it can also be corrected with a small amount of buffer quite easily. do tannic acids bother amphibians, specifically Cynops?