as an illustrator, I use acrylic paints a lot and have talked to representatives of both Liquitex and GOLDEN acrylics. After acrylic has dried fully, chemicals are stuck within the polymer. however, extended submersion in water does eventually break down the polymers. the "basics" line is Lquitex's lower grade paint and I tend to avoid it because it has inferior consistency and coverage... but it's cheaper. Also, many acrylics are transparent or translucent and are designed for glazing not coverage... look at the labels, they usually let you know what the transparency of a color will be and whether or not it has any heavy metals.
the problem with any paint is that many of the pigments are derived from heavy metals. I don't even use cadmium based paints for illustrations because they are just too toxic.