I don't know about where to get one is australia, but i'm pretty sure most companies will be willing to ship one.
I can however help you on how they work.
Ice probes use a think called a "peltier diode" or commonly call a Thermo electric cooler (TEC).
I believe the ice probes use a 50w peltier which is exactly the same as what you would find in most 12v car fridges.
TEC's are made up of hundreds of thermocouples (two dissimilar metals used to measure temperature) and by applying voltage it will get hot one side and cold the other, reverse polarity and the opposite will happen.
The peltier is mounted between a heatsink and
the cooling probe.
As for effectiveness i found a site a while ago that claimed that one 50w ice probe was capable of chilling a 40 liter aquarium by 6-8 degrees.
So one Ice probe should easily cool your 20L tank.
Mounting however will be where it gets interesting. They are designed for acrylic tanks, where a hole is drilled in the side of the aquarium. I have seen a post on this site of someone who had managed to suspend theirs in the top of the tank with the heat sink above the water line.
I'm currently in the process of building my own peltier powerd cooler with 3 x 75watt peltiers when its finished I'll post some photos for everyone (not long now only have the power supply to finish)
Hope this helps