I just built my first terrarium for some blue spotted salamanders I'm planning on purchasing. I used some large patches of live moss I had collected from outside several months ago, and some rocks from my parents backyard. The issue I'm worried about is the rock in central pennsylvania is a mixture of slate and limestone. I poured some rice vinegar over the rocks and no bubbling. I was wondering if limestone would be dangerous for terrestrial salamanders. Should I just switch to wood? I was thinking rock might be better for keeping the salamanders cool? Any advice would be appreciated. Thanks =).
Slate is perfectly fine. Limestone should be used with caution in terrestrial enclosures. (and only in aquatic enclosures for certain hard water species).
Also, vinegar is not a suitable test for the presence of calcium carbonate. The acetic acid is not strong enough to give accurate results. the best acid test is to use muriatic acid from a pool supply shop, however this strong acid is dangerous to use. The most user friendly and easy way to check rock for calcium carbonate is to place a few drops of pH Down (an aquarium product for adjusting pH). Since you are keeping terrestrial salamanders, you really do not need to worry about calcium carbonate though.
As an old Pennsylvania boy myself, I can assure you the biggest worry you have in central PA is the presence of hydrocarbons in the rocks there. This is easy to test for though, merely break a piece of the edge of the stone and smell the "fresh face" if it smells oily or gassy, better off using it on your patio. The "fizz" test will come in handy for you too as shale, which is probably the most common sedimentary rock in your area does not fizz. It also is the most likely to contain hydrocarbons.
Rocks and wood will do little to keep you pets cool in captivity. Better to keep the enclosure in the basement or have air conditioning available.
Any found rock or wood should be scrubbed and then boiled for a few hours in tap water to kill off any possibly harmful fungi, bacteria, and parasites.
Limestone can only harm salamanders by smashing them. It is as safe as a stone can be in the tank.
For most terrestrial caudates this is somewhat true. For most aquatic caudates this is a dangerous falsehood.
Limestone is a raw form of calcium carbonate, which is water soluble and will cause
uncontrollable and random rises in pH and water hardness. With exception to the few hard water caudates out there, it is an unwise choice for most hobbyists in most enclosures.