Spaghnum peat moss does retain moisture. The caveat is that it also contributes acidity to the enclosure...and I think that is key...a vivarium is a moist, finite enclosure. I think there are too many variables to say with assuredness that it can safely be used. Spaghnums are used to augment the pH of soils and can be particularly useful if working with alkaline soils. Spaghnum peat moss has a low pH that in general is around 5.5 (can vary depending on where it is harvested from). Acid environments aren't suitable for most sals...i.e., risk. I wouldn't use for those reasons and creating stress for my sals. A small patch in a large enclosure may not be an issue, in a small enclosure where substrate is not frequently changed, could be an issue...again, too many variables. In the interest of the health of your animal(s), you could always measure the pH to see what your spaghnum is or is not doing to the substrate.